File(s) not publicly available
A Non-Metallocene Hydride of Titanium (III)
journal contribution
posted on 2023-06-07, 19:56 authored by Jason B Love, Howard C S Clark, Geoff Cloke, Jennifer C Green, Peter B HitchcockSeveral titanium(m) complexes incorporating the chelating diamidoamine ligand [(Me3SiNCH2CH2)2NSiMe3]2-[NN2] are described. The reaction between Li2[NN2] and TiCl3(THF)3 (THF = tetrahydrofuran) resulted in the formation of the dimeric titanium(III) chloride {TiCl[NN2]}2 1, from which the monomeric titanium(III) alkyl Ti{CH(SiMe3)2}[NN2] 2 could be synthesized via a salt metathesis route. The alkyl complex 2 was found to react with hydrogen gas to form the thermally stable, dimeric, diamagnetic titanium(III) hydride {TiH[NN2]}2 3; density functional calculations on a simplified model system of 3 indicated the presence of a weak Ti-Ti s- interaction. The solid-state structures of 1, 2, and 3 are described.
History
Publication status
- Published
Journal
Journal of the American Chemical SocietyISSN
00027863Publisher
Journal of the American Chemical SocietyExternal DOI
Issue
29Volume
121Page range
6843 - 6849ISBN
0002-7863Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
Categories
No categories selectedKeywords
Licence
Exports
RefWorks
BibTeX
Ref. manager
Endnote
DataCite
NLM
DC