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Syntheses of the novel cage compounds P3Se3C3But3 and P3Se4C3But3 and an unusual insertion reaction of [PtCl2(PMe3)] into the Se-Se bond of the latterto give the six-coordinate Pt(IV) complex [PtCl2(PMe3)P3Se4C3But3]

journal contribution
posted on 2023-06-07, 19:59 authored by Peter B Hitchcock, John F Nixon, Nurgun Sakarya
The novel cage compounds P3Se3C3But3 and P3Se4C3But3 are formed (together with the 1,2,4-selenadiphosphole P2SeC2But2) from the reaction of the phosphaalkyne ButCP with selenium; the [PtCl2(PMe3)] fragment undergoes an unusual insertion reaction into the Se–Se bond of P3Se4C3- But3.

History

Publication status

  • Published

Journal

Chemical Communications

ISSN

1359-7345

Publisher

Royal Society of Chemistry

Volume

18

Page range

1745 - 1746

ISBN

1359-7345

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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