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Poly{guanidinium} Salts: Application in the Preparation of a Coordinatively Saturated Aluminium Cation

journal contribution
posted on 2023-06-08, 00:30 authored by Pedro J Aragón Saez, Sarah H Oakley, Martyn P Coles, Peter B Hitchcock
Protonation of the linked bis(guanidine), H2C{hpp}2, affords isolated guanidinium salts that have been used to prepare a coordinatively saturated aluminium cation.

History

Publication status

  • Published

Journal

Chemical Communications

ISSN

1359-7345

Issue

8

Volume

8

Page range

816 - 818

Pages

3.0

Department affiliated with

  • Chemistry Publications

Notes

MPC directed all aspect of this work and is the corresponding author. A novel synthetic route to cationic main group complexes with many potential applications in catalysis. Structurally characterized guanidine/guanidinium and bis-guanidinium salts allowing detailed analysis of bonding in the solid-state.

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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