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The first example of simple oxidative addition of an aryl chloride to a discrete palladium (n-heterocyclic carbene) amination precatalyst
journal contribution
posted on 2023-06-08, 08:11 authored by Stephen Caddick, Geoff Cloke, Peter B Hitchcock, John Leonard, Alexandra K de K Lewis, Darren McKerrecher, Lisa R TitcombThe oxidative addition of an aryl chloride to a discrete palladium n-heteocyclic carbene amination precatalyst, was discussed. It was found that the oxidative addition of 4-chlorotoluene to Pd(0) resulted in the formation of not a four-coordinate complex but rather the arylated imidazolium salt. The identity of imidazolium salt was confirmed by x-ray crystallography.
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Publication status
- Published
Journal
OrganometallicsISSN
02767333Publisher
ACS PublicationsExternal DOI
Issue
21Volume
21Page range
4318-4319Pages
2.0Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
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