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A Gas-Phase Study of the Preferential Solvation of Mn2+ in Mixed Water/Methanol Clusters
journal contribution
posted on 2023-06-08, 08:44 authored by Bridgette J Duncombe, Jens O S Ryden, Ljiljana Puskar, Hazel CoxHazel Cox, Anthony J StaceThe kinetic shift that exists between two competing unimolecular fragmentation processes has been used to establish whether or not gas-phase Mn2+ exhibits preferential solvation when forming mixed clusters with water and methanol. Supported by molecular orbital calculations, these first results for a metal dication demonstrate that Mn2+ prefers to be solvated by methanol in the primary solvation shell.
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Publication status
- Published
Journal
Journal of the American Society for Mass SpectrometryISSN
1044-0305Publisher
SpringerExternal DOI
Issue
4Volume
19Page range
520-530Pages
11.0Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
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