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Ligating similarities between the novel five-electron-donor h 4-P3C2But2(R)H ring system (R=CH(SiMe3)2) and the h 5-cyclopentadienyl ring. Syntheses crystal and molecular structures of[Co2(CO)5( m -P3C2But2CH(SiMe3)2)] and [Co(CO)2( h 4-P3C2But2H(CH(S
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posted on 2023-06-08, 09:39 authored by Peter B Hitchcock, John F Nixon, Nurgun SakaryaTreatment of the 1,2,4-triphosphole, P3C2But2(CH(SiMe3)2), with [Co2(CO)8] in THF under mild conditions affords the binuclear complex [Co2(CO)5(µ-P3C2But2CH(SiMe3)2)], in which the ring acts as a six-electron-donor. Under slightly more vigorous reaction conditions an H-transfer reaction occurs (presumably from the solvent) to afford the mononuclear compound [Co(CO)2(P3C2But2H(CH(SiMe3)2)] containing an ?4-ligated five-electron-donor P3C2But2H(CH(SiMe3)2 ring system. The molecular structures of both compounds have been determined by single-crystal X-ray diffraction studies.
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Publication status
- Published
Journal
Journal of Organometallic ChemistryISSN
0022-328XPublisher
ElsevierExternal DOI
Volume
601Page range
335 - 340ISBN
0022-328XDepartment affiliated with
- Chemistry Publications
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- No
Peer reviewed?
- Yes
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2012-02-06Usage metrics
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