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Synthesis and electronic structure of the first cyaphide-alkynyl complexes

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posted on 2023-06-08, 17:27 authored by Nicola Trathen, Matthew C Leech, Ian CrossleyIan Crossley, Victoria K Greenacre, S Mark Roe
The novel complexes trans-[Ru(dppe)2(CCR)(CP)] (R = CO2Me, C6H4OMe), the first to incorporate cyaphide as part of a conjugated system, are obtained in facile manner. The electronic structure of these compounds is probed by X-ray, DFT and UV/Vis studies.

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Publication status

  • Published

File Version

  • Accepted version

Journal

Dalton Transactions

ISSN

1477-9226

Publisher

Royal Society of Chemistry

External DOI

Issue

24

Volume

43

Page range

9004-9007

Department affiliated with

  • Chemistry Publications

Full text available

  • Yes

Peer reviewed?

  • Yes

Legacy Posted Date

2014-06-02

First Open Access (FOA) Date

2018-08-15

First Compliant Deposit (FCD) Date

2019-07-02

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