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Synthesis of unsymmetrical NCN' and PCN pincer palladacycles and their catalytic evaluation compared with a related SCN pincer palladacycle

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posted on 2023-06-21, 06:01 authored by Gavin Roffe, Graham J Tizzard, Simon J Coles, Hazel CoxHazel Cox, John SpencerJohn Spencer
1-(3-(Pyridin-2-yl)phenyl)methanamine derivatives have been synthesized and underwent C–H bond activation to afford unsymmetrical NCN' pincer palladacycles, which were characterised in the solid state. 2-Pyridinyl-phenol and -benzyl alcohols were then used as precursors to unsymmetrical PCN pincer palladacycles. Catalytic applications, where the palladacycle remains in the Pd(II) state, have been carried out and show good activity and selectivity.

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Publication status

  • Published

File Version

  • Published version

Journal

Organic Chemistry Frontiers

ISSN

2052-4110

Publisher

Royal Society of Chemistry

Issue

8

Volume

3

Page range

957-965

Department affiliated with

  • Chemistry Publications

Full text available

  • Yes

Peer reviewed?

  • Yes

Legacy Posted Date

2016-06-20

First Open Access (FOA) Date

2017-01-23

First Compliant Deposit (FCD) Date

2016-06-18

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