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Synthesis of unsymmetrical NCN' and PCN pincer palladacycles and their catalytic evaluation compared with a related SCN pincer palladacycle
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posted on 2023-06-21, 06:01 authored by Gavin Roffe, Graham J Tizzard, Simon J Coles, Hazel CoxHazel Cox, John SpencerJohn Spencer1-(3-(Pyridin-2-yl)phenyl)methanamine derivatives have been synthesized and underwent C–H bond activation to afford unsymmetrical NCN' pincer palladacycles, which were characterised in the solid state. 2-Pyridinyl-phenol and -benzyl alcohols were then used as precursors to unsymmetrical PCN pincer palladacycles. Catalytic applications, where the palladacycle remains in the Pd(II) state, have been carried out and show good activity and selectivity.
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- Published
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- Published version
Journal
Organic Chemistry FrontiersISSN
2052-4110Publisher
Royal Society of ChemistryExternal DOI
Issue
8Volume
3Page range
957-965Department affiliated with
- Chemistry Publications
Full text available
- Yes
Peer reviewed?
- Yes
Legacy Posted Date
2016-06-20First Open Access (FOA) Date
2017-01-23First Compliant Deposit (FCD) Date
2016-06-18Usage metrics
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