catalysts-06-00140.pdf (1.44 MB)
Highly efficient tetranuclear ZnII2LnIII2 catalysts for the Friedel-Crafts alkylation of indoles and nitrostyrenes
Version 2 2023-06-12, 06:43
Version 1 2023-06-09, 02:42
journal contribution
posted on 2023-06-12, 06:43 authored by Prashant Kumar, Smaragda Lymperopoulou, Kieran Griffiths, Stavroula Sampani, George KostakisGeorge KostakisWe demonstrate for the first time the high efficacy of tetranuclear ZnII2LnIII2 coordination clusters (CCs) as catalysts for the Friedel–Crafts (FC) alkylation of indoles with a range of trans-ß-nitrostyrenes. The reaction proceeds in good to excellent yields (76%–99%) at room temperature with catalyst loadings as low as 1.0 mol %.
Funding
Defect dicubane 3d/Dy(III) Coordination Clusters: Heading for materials displaying catalytic properties; G1632; EPSRC-ENGINEERING & PHYSICAL SCIENCES RESEARCH COUNCIL; EP/M023834/1
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Publication status
- Published
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- Published version
Journal
CatalystsISSN
2073-4344Publisher
MDPIExternal DOI
Issue
9Volume
6Department affiliated with
- Chemistry Publications
Full text available
- Yes
Peer reviewed?
- Yes
Legacy Posted Date
2016-09-01First Open Access (FOA) Date
2016-11-17First Compliant Deposit (FCD) Date
2016-09-01Usage metrics
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