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Synthesis of functionalized hydrazines: facile homogeneous (n-heterocyclic carbene)-palladium(0)-catalyzed diboration and silaboration of azobenzenes

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posted on 2023-06-09, 03:59 authored by Melvyn B Ansell, George KostakisGeorge Kostakis, Holger Braunschweig, Oscar Navarro Fernandez, John SpencerJohn Spencer
The bis(N-heterocyclic carbene)(diphenylacetylene)palladium complex [Pd(ITMe)2(PhC=CPh)] (ITMe=1,3,4,5 tetramethylimidazol-2-ylidene) acts as a highly active pre catalyst in the diboration and silaboration of azobenzenes to synthesize a series of novel functionalized hydrazines. The reactions proceed using commercially available diboranes and silaboranes under mild reaction conditions.

Funding

DTA - University of Sussex 2013 (EPSRC); G1142; EPSRC-ENGINEERING & PHYSICAL SCIENCES RESEARCH COUNCIL; EP/L505109/1

History

Publication status

  • Published

File Version

  • Published version

Journal

Advanced Synthesis and Catalysis

ISSN

1615-4150

Publisher

Wiley-VCH Verlag

Issue

23

Volume

358

Page range

3765-3769

Department affiliated with

  • Chemistry Publications

Full text available

  • Yes

Peer reviewed?

  • Yes

Legacy Posted Date

2016-11-14

First Open Access (FOA) Date

2016-11-14

First Compliant Deposit (FCD) Date

2016-11-12

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