Retention of Pt->B Bonding in Oxidative Addition Reactions of the Platinaboratrane [Pt(PPh3){B(mt)3}](Pt¿B)10 (mt = Methimazolyl)

Crossley, Ian R, Hill, Anthony F and Willis, Anthony C (2008) Retention of Pt->B Bonding in Oxidative Addition Reactions of the Platinaboratrane [Pt(PPh3){B(mt)3}](Pt¿B)10 (mt = Methimazolyl). Organometallics, 27 (3). pp. 312-315. ISSN 0276-7333

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Abstract

The platinaboratrane [Pt(PPh3){B(mt)3}](PtB)10 (mt = methimazolyl) is prone to oxidative addition reactions with a range of substrates (Cl2, Br2, I2, HCl, CH3I) without disrupting the platinum-boron dative bond, as illustrated by the first structurally characterized platinaboratranes [PtH(PPh3){B(mt)3}]Cl(PtB)8 and [PtI2{B(mt)3}](PtB)8.

Item Type: Article
Additional Information: Sole experimentalist, other authors = group PI (AFH) and crystallographer
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science
Depositing User: Ian Crossley
Date Deposited: 06 Feb 2012 18:27
Last Modified: 03 Oct 2012 10:56
URI: http://srodev.sussex.ac.uk/id/eprint/16410
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