Unlocking the metallaboratrane cage: reversible B-H activation in platinaboratranes.

Crossley, Ian R and Hill, Anthony F (2008) Unlocking the metallaboratrane cage: reversible B-H activation in platinaboratranes. Dalton Transactions (2). pp. 201-203. ISSN 1477-9226

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Abstract

The reaction of the new platinaboratrane salt [PtH(PTol3){B(mt)3}]Cl(Pt-->B)8 (mt = methimazolyl, Tol = C6H4Me-4) with 2 equivalents of PR3 (R = Me, Et) affords, via hydride migration to boron and ligand substitution, the salts [Pt(PR3)2{kappa 2-S,S'-HB(mt)3}]Cl, which slowly undergo B-H reactivation, to afford, ultimately, the platinaboratrane salts [PtH(PR3){B(mt)3}]Cl(Pt-->B)8.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science
Depositing User: Ian Crossley
Date Deposited: 06 Feb 2012 19:17
Last Modified: 03 Oct 2012 10:59
URI: http://srodev.sussex.ac.uk/id/eprint/19950
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