University of Sussex
Browse

File(s) not publicly available

Unlocking the metallaboratrane cage: reversible B-H activation in platinaboratranes.

journal contribution
posted on 2023-06-07, 22:28 authored by Ian CrossleyIan Crossley, Anthony F Hill
The reaction of the new platinaboratrane salt [PtH(PTol3){B(mt)3}]Cl(Pt-->B)8 (mt = methimazolyl, Tol = C6H4Me-4) with 2 equivalents of PR3 (R = Me, Et) affords, via hydride migration to boron and ligand substitution, the salts [Pt(PR3)2{kappa 2-S,S'-HB(mt)3}]Cl, which slowly undergo B-H reactivation, to afford, ultimately, the platinaboratrane salts [PtH(PR3){B(mt)3}]Cl(Pt-->B)8.

History

Publication status

  • Published

Journal

Dalton Transactions

ISSN

1477-9226

Issue

2

Page range

201-203

Pages

3.0

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

Usage metrics

    University of Sussex (Publications)

    Categories

    No categories selected

    Exports

    RefWorks
    BibTeX
    Ref. manager
    Endnote
    DataCite
    NLM
    DC