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[60]- and [70]Fullerenes are trifluoromethylated across 5 : 6-bonds
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posted on 2023-06-07, 22:38 authored by Adam D Darwish, Anthony G Avent, Ala'a K Abdul-Sada, Roger TaylorTrifluoromethylation of[60]- and [70]fullerenes occurs across both 6:6- and 5: 6- bonds giving unsymmetrical tetramethyl adducts having four contiguous CF3 groups; both fullerenes give bis adducts which do not involve 6: 6-addition, and unsymmetrical hexa-adducts (with contiguous CF3 groups) are also obtained from [60] fullerene.
History
Publication status
- Published
Journal
Chemical CommunicationsISSN
1359-7345Publisher
Royal Society of ChemistryExternal DOI
Issue
12Volume
21Page range
1374-1375Pages
12.0Department affiliated with
- Chemistry Publications
Notes
AAS performed the MS measurements in collaboration with the late RT and co-authored the paperFull text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
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