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New aspects of the Hunsdiecker-Barton halodecarboxylation¿syntheses of phospha-shikimic acid and derivatives
journal contribution
posted on 2023-06-08, 00:05 authored by Benoit Carbain, Peter B Hitchcock, Hansjorg StreicherWe report an efficient synthetic approach to phospha-isosteres of important intermediates of the shikimic acid pathway by the application of the HunsdieckerBarton halodecarboxylation to cyclohexenylcarboxylic acids. As examples, phospha-shikimic acid, its 3-dehydro derivative and the respective monomethyl esters were synthesized. The approach has proven equally useful in the synthesis of isosteres of the antiviral agent oseltamivir.
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Publication status
- Published
Journal
Tetrahedron LettersISSN
0040-4039External DOI
Issue
20Volume
51Page range
2717-2719Pages
3.0Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
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