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The first structurally charcterised solvent-free sigma -bonded diorganocalcium Ca[C(SiMe 3 ) 3 ] 2
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posted on 2023-06-08, 00:07 authored by Colin Eaborn, Simon A Hawkes, Peter B Hitchcock, J David SmithThe monomeric solvent-free compound CaR2 1 [R = C(SiMe3)3] is obtained as colourless air- and moisturesensitive crystals from the reaction between KR and CaI2; in the solid the C–Ca–C axis is bent with Ca–C 2.459(9) Å and C–Ca–C 149.7(6)°; reactions of 1 with ethers ROEt give RH, ethene and Ca(OEt)2.
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Publication status
- Published
Journal
Chemical CommunicationsISSN
1359-7345Publisher
Royal Society of ChemistryExternal DOI
Volume
20Page range
1961 - 1962ISBN
1359-7345Department affiliated with
- Chemistry Publications
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- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
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