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Remarkable carbene-induced transformation of 246-tri- tert -butyl-135-triphosphabenzene P3C3But3 to the 124-triphosphole P3C2But2CBut(carbene). Crystal and molecular structure of the planar triphosphole complex[Mo(CO)3( h 5-P3C2But2CBut(carbene))

journal contribution
posted on 2023-06-08, 06:04 authored by Scott B Clendenning, Peter B Hitchcock, John F Nixon, Laszlo Nyulászi
Treatment of 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene, P3C3But3, with the stable carbene 1,3,4,5-tetramethylimidazol-2-ylidene affords the planar 1,2,4-triphosphole, P3C2But2CBut(carben e), [carbene = C(N(Me)C(Me)C(Me)N(Me))] which has been structurally characterised as its ?5- ligated [Mo(CO)3] complex; theoretical calculations are presented on the mechanism of this novel reaction.

History

Publication status

  • Published

Journal

Chemical Communications

Publisher

Chemical Communications

Volume

14

Page range

1305 - 1306

ISBN

1359-7345

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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