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UIII-Induced Reductive Co-Coupling of NO and CO to Form UIV Cyanate and Oxo Derivates
journal contribution
posted on 2023-06-08, 06:10 authored by Alistair S P Frey, Geoff Cloke, Martyn P Coles, Peter B HitchcockCO and NO give NCO and O! Sequential treatment of [U(¿-C8H6{SiiPr3-1,4}2)(¿-Cp*)] with CO followed by NO (or vice versa) affords a mixture of the bridging cyanate complex [{U(¿-C8H6{SiiPr3-1,4}2)(¿-Cp*)}2(µ-OCN)2] and the bridging oxo complex [{U(¿-C8H6{SiiPr3-1,4}2)(¿-Cp*)}2(µ-O)], both of which have been structurally characterised (see scheme).
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Publication status
- Published
Journal
Chemistry - A European JournalISSN
0947-6539External DOI
Issue
31Volume
16Page range
9446-9448Pages
3.0Department affiliated with
- Chemistry Publications
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- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
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