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UIII-Induced Reductive Co-Coupling of NO and CO to Form UIV Cyanate and Oxo Derivates

journal contribution
posted on 2023-06-08, 06:10 authored by Alistair S P Frey, Geoff Cloke, Martyn P Coles, Peter B Hitchcock
CO and NO give NCO and O! Sequential treatment of [U(¿-C8H6{SiiPr3-1,4}2)(¿-Cp*)] with CO followed by NO (or vice versa) affords a mixture of the bridging cyanate complex [{U(¿-C8H6{SiiPr3-1,4}2)(¿-Cp*)}2(µ-OCN)2] and the bridging oxo complex [{U(¿-C8H6{SiiPr3-1,4}2)(¿-Cp*)}2(µ-O)], both of which have been structurally characterised (see scheme).

History

Publication status

  • Published

Journal

Chemistry - A European Journal

ISSN

0947-6539

Issue

31

Volume

16

Page range

9446-9448

Pages

3.0

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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