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Surprising reactions of a 2H-azaphosphirene complex with a silylene

journal contribution
posted on 2023-06-08, 06:28 authored by Emmanuel Ionescu, Barbara Gehrhus, Peter B Hitchcock, Martin Nieger, Rainer Streubel
Reaction of the 2H-azaphosphirene complex 1 with the silylene 5 yielded the bicyclic carbene complex 9 as sole product at ambient temperature; the reaction was less selective at elevated temperatures; additionally, the synthesis and structure of the first 1,2,4,3-azadiphosphasilol-5-ene complex 11 is presented.

History

Publication status

  • Published

Journal

Chemical Communications

ISSN

1359-7345

Publisher

Royal Society of Chemistry

Issue

38

Volume

38

Page range

4842-4844

Pages

3.0

Department affiliated with

  • Chemistry Publications

Notes

PH solved the crystal structures relevant to this paper and contributed to the mechanistic discussion, part of collaborative project between BG and RS

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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