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Structural diversity in organolithium -sodium and -potassium cycanocuprates

journal contribution
posted on 2023-06-08, 07:07 authored by Colin Eaborn, Michael S Hill, Peter B Hitchcock, J David Smith
An unprecedented series of “lower order” alkali metal (Li, Na, K) cyanocuprates containing the bulky (Me2PhSi)3C ligand has been synthesized. Both monomeric and dimeric forms of the lithium derivative have been characterized; the tetrameric potassium compound provides a striking example of molecular self-assembly driven by K-p-aryl interactions.

History

Publication status

  • Published

Journal

Organometallics

ISSN

0276-7333

Publisher

American Chemical Society

Volume

19

Page range

5780-5783

ISBN

0276-7333

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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