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Larch, Christopher P, Cloke, F Geoffrey N and Hitchcock, Peter B (2008) Activation and reduction of diethyl ether by low valent uranium: formation of the trimetallic, mixed valence uranium oxo species [U(CpRR)(µ-I)2]3(µ3-O) (CpRR = C5Me5, C5Me4H, C5H4SiMe3). Chemical Communications, 44 (1). pp. 82-84. ISSN 1364-548X
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Official URL: http://dx.doi.org/10.1039/B714211K
Abstract
The reaction of UI3 and KCpRR' (CpRR' = pentamethylcyclopentadienyl, trimethylsilylcyclopentadienyl or tetramethylcyclopentadienyl) in diethyl ether results in the two-electron reduction of the solvent to form trimetallic, mixed valence uranium oxo species.
Item Type: | Article |
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Schools and Departments: | School of Life Sciences > Chemistry |
Subjects: | Q Science |
Depositing User: | Geoff Cloke |
Date Deposited: | 06 Feb 2012 20:54 |
Last Modified: | 02 Jul 2013 12:58 |
URI: | http://srodev.sussex.ac.uk/id/eprint/28678 |