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Structural and Catalytic Properties of Bis(guanidine)copper(I) Halides

journal contribution
posted on 2023-06-08, 08:15 authored by Sarah H Oakley, Martyn P Coles, Peter B Hitchcock
The neutral, bicyclic guanidine 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine (hppH) coordinates to Cu(I) halides via the imine nitrogen, and the complexes are stabilized by intramolecular NX interactions (X = Cl, Br) or are partially dissociated (X = I) in the solid state; in all cases, fluxional behavior is observed in solution. Selected complexes have been tested as catalysts for the polymerization of methyl methacrylate.

History

Publication status

  • Published

Journal

Inorganic Chemistry

ISSN

0020-1669

Publisher

ACS Publications

Issue

10

Volume

42

Page range

3154 - 3156

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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