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Structural and Catalytic Properties of Bis(guanidine)copper(I) Halides
journal contribution
posted on 2023-06-08, 08:15 authored by Sarah H Oakley, Martyn P Coles, Peter B HitchcockThe neutral, bicyclic guanidine 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine (hppH) coordinates to Cu(I) halides via the imine nitrogen, and the complexes are stabilized by intramolecular NX interactions (X = Cl, Br) or are partially dissociated (X = I) in the solid state; in all cases, fluxional behavior is observed in solution. Selected complexes have been tested as catalysts for the polymerization of methyl methacrylate.
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Publication status
- Published
Journal
Inorganic ChemistryISSN
0020-1669Publisher
ACS PublicationsExternal DOI
Issue
10Volume
42Page range
3154 - 3156Department affiliated with
- Chemistry Publications
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- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
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