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Palladium catalyzed arylation reactions of meta photocycloadducts

journal contribution
posted on 2023-06-08, 08:21 authored by Clive S Penkett, Rupert O Sims, Richard French, Lauriane Dray, Stephen J Roome, Peter B Hitchcock
We describe the first application of a Heck arylation reaction being performed on a meta photocycloadduct. The resulting arylation/fragmentation process leads to the formation of a bridged bicyclic ketone and constitutes a dramatic increase in molecular complexity after just two synthetic operations.

History

Publication status

  • Published

Journal

Chemical Communications

ISSN

1359-7345

Publisher

Royal Society of Chemistry

Issue

17

Volume

17

Page range

1932-1933

Pages

2.0

Department affiliated with

  • Chemistry Publications

Notes

CSP directed the work and is the corresponding author. Paper describes the first example of a unique carbon-carbon bond forming reaction involving metaphotocycloadducts.

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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