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Synthesis and reactivity of tin amide complexes
journal contribution
posted on 2023-06-08, 08:24 authored by Lisa A-M Harris, Martyn P Coles, J Robin FultonA terminal tin amide and a terminal tin anilide complex, (BDI)SnN(iPr 2) and (BDI)SnN(H)Ar (Ar = 2,6-iPr2C 6H3), respectively, have been synthesized utilizing the bulky ß-diketiminate ligand, [{N(2,6-iPr2C 6H3)C(Me)}2CH]-, or BDI, to stabilize the low coordinate divalent tin metal center. Only (BDI)SnN(iPr 2) reacts with phenylacetylene to yield (BDI)SnCCPh, but both species react with methyl triflate to give (BDI)SnOTf and carbon dioxide, resulting in the formation of (BDI)SnOC(O)N(iPr2) and (BDI)SnOC(O)N(H)Ar.
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Publication status
- Published
Journal
Inorganica Chimica ActaISSN
00201693Publisher
ElsevierExternal DOI
Issue
1Volume
369Page range
97-102Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
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