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Synthesis and reactivity of tin amide complexes

journal contribution
posted on 2023-06-08, 08:24 authored by Lisa A-M Harris, Martyn P Coles, J Robin Fulton
A terminal tin amide and a terminal tin anilide complex, (BDI)SnN(iPr 2) and (BDI)SnN(H)Ar (Ar = 2,6-iPr2C 6H3), respectively, have been synthesized utilizing the bulky ß-diketiminate ligand, [{N(2,6-iPr2C 6H3)C(Me)}2CH]-, or BDI, to stabilize the low coordinate divalent tin metal center. Only (BDI)SnN(iPr 2) reacts with phenylacetylene to yield (BDI)SnCCPh, but both species react with methyl triflate to give (BDI)SnOTf and carbon dioxide, resulting in the formation of (BDI)SnOC(O)N(iPr2) and (BDI)SnOC(O)N(H)Ar.

History

Publication status

  • Published

Journal

Inorganica Chimica Acta

ISSN

00201693

Publisher

Elsevier

Issue

1

Volume

369

Page range

97-102

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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