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Synthesis, crystal and molecular structures of the novel, structurally different, cage compounds P6C4Bu(t)4SiI2 and P6C4Bu(t)4GeI2, resulting from intra-molecular coupling of two 1,2,4-triphospholyl rings
journal contribution
posted on 2023-06-08, 08:25 authored by Anthony G Avent, Geoff Cloke, Matthew D Francis, Peter B Hitchcock, John F NixonTreatment of EI4 (E = Si or Ge) with 2 equivalents of K[P3C2Bu(t)2] affords the novel cage compounds P6C4Bu(t)4SiI2 and P6C4Bu(t)4GeI2 respectively, whose molecular structures, determined spectroscopically and by single crystal X-ray diffraction studies, are different both in solution and in the solid state.
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Publication status
- Published
Journal
Chemical CommunicationsISSN
13597345Publisher
RSC PublishingExternal DOI
Issue
10Page range
879-880Department affiliated with
- Chemistry Publications
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- No
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- Yes
Legacy Posted Date
2012-02-06Usage metrics
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