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Variable coordination chemistry of the phospha(III)guanidinate anion; application as a metal-functionalised phosphine ligand

journal contribution
posted on 2023-06-08, 09:59 authored by Martyn Coles, Peter Hitchcock
Structural investigation of Li-complexes of the phospha(III)-guanidinate anion [Ph2PC{(NPr)-Pr-i}(2)](-) revealed variable coordination to lithium; synthesis of the dimethyl aluminium compound, (Ph2PC{(NPr)-Pr-i}(2))AlMe2, which behaves as a metal-functionalised phosphine ligand towards platinum, is reported.

History

Publication status

  • Published

Journal

Chemical Communications

ISSN

1359-7345

Publisher

RSC Publishing

Issue

23

Volume

-

Page range

2794-2795

Department affiliated with

  • Chemistry Publications

Notes

MPC conducted all synthetic work and is the corresponding author. The first study of different bonding modes of the phosphaguanidinate anion within lithium complexes. A new class of metal functionalized phosphine ligand incorporated into a hetero-trimetallic complex.

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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