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Variable coordination chemistry of the phospha(III)guanidinate anion; application as a metal-functionalised phosphine ligand
journal contribution
posted on 2023-06-08, 09:59 authored by Martyn Coles, Peter HitchcockStructural investigation of Li-complexes of the phospha(III)-guanidinate anion [Ph2PC{(NPr)-Pr-i}(2)](-) revealed variable coordination to lithium; synthesis of the dimethyl aluminium compound, (Ph2PC{(NPr)-Pr-i}(2))AlMe2, which behaves as a metal-functionalised phosphine ligand towards platinum, is reported.
History
Publication status
- Published
Journal
Chemical CommunicationsISSN
1359-7345Publisher
RSC PublishingExternal DOI
Issue
23Volume
-Page range
2794-2795Department affiliated with
- Chemistry Publications
Notes
MPC conducted all synthetic work and is the corresponding author. The first study of different bonding modes of the phosphaguanidinate anion within lithium complexes. A new class of metal functionalized phosphine ligand incorporated into a hetero-trimetallic complex.Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
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