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Rapid and selective catalytic oxidation of secondary alcohols at room temperature by using (N-heterocyclic carbene)-ni(0) systems
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posted on 2023-06-08, 12:31 authored by Christophe Berini, Ole H Winkelmann, Jennifer Otten, David A Vicic, Oscar NavarroThe selective, anaerobic catalytic oxidation of secondary alcohols at room temperature by using an in situ (N-heterocyclic carbene)-Ni(0) system is presented. The use of non-anhydrous, non-degassed 2,4-dichlorotoluene as both the oxidant and the solvent allows for very short reaction times and very high yields. In addition, a well-defined (N-heterocyclic carbene)-Ni(0) complex was synthesized and applied to these oxidation reactions.
History
Publication status
- Published
Journal
Chemistry - A European JournalISSN
0947-6539Publisher
WileyExternal DOI
Issue
23Volume
16Page range
6857-6860Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-10-26Usage metrics
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