Penkett, Clive S, Brann, Paul J, Woolford, Jason A and Kahan, Rachel J (2013) Confirming the existence of π-allyl-palladium intermediates during the reaction of meta photocycloadducts with palladium(ii) compounds. Chemical Communications, 49 (11). pp. 1106-1108. ISSN 1359-7345
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Abstract
The transient existence of π-allyl-palladium intermediates formed by the reaction of Pd(OAc)2 and anisole-derived meta photocycloadducts has been demonstrated using NMR techniques. The intermediates tended to be short-lived and underwent rapid reductive elimination of palladium metal to form allylic acetates, however this degradation process could be delayed by changing the reaction solvent from acetonitrile to chloroform.
Item Type: | Article |
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Schools and Departments: | School of Life Sciences > Chemistry |
Subjects: | Q Science > QD Chemistry |
Depositing User: | Rachel Kahan |
Date Deposited: | 27 Feb 2013 11:49 |
Last Modified: | 07 Mar 2017 07:12 |
URI: | http://srodev.sussex.ac.uk/id/eprint/43835 |
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