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Bobin, Mariusz, Day, Iain J, Roe, Stephen M and Viseux, Eddy M E (2013) Insights into the mechanism for gold catalysis: behaviour of gold(i) amide complexes in solution. Dalton Transactions, 42 (18). pp. 6592-6602. ISSN 1477-9226
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Official URL: http://dx.doi.org/10.1039/C3DT33039G
Abstract
We report the synthesis and activity of new mononuclear and dinuclear gold amide complexes . The dinuclear complexes and were characterised by single crystal X-ray analysis. We also report solution NMR and freezing point depression experiments to rationalise their behaviour in solution and question the de-ligation process invoked in gold catalysis.
Item Type: | Article |
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Schools and Departments: | School of Life Sciences > Chemistry |
Subjects: | Q Science Q Science > QD Chemistry Q Science > QD Chemistry > QD0071 Analytical chemistry Q Science > QD Chemistry > QD0146 Inorganic chemistry Q Science > QD Chemistry > QD0241 Organic chemistry Q Science > QD Chemistry > QD0450 Physical and theoretical chemistry R Medicine > RC Internal medicine > RC0254 Neoplasms. Tumors. Oncology Including cancer and carcinogens |
Related URLs: | |
Depositing User: | Deeptima Massey |
Date Deposited: | 20 Mar 2013 11:10 |
Last Modified: | 07 Mar 2017 11:07 |
URI: | http://srodev.sussex.ac.uk/id/eprint/44093 |
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