(N-heterocyclic carbene)-Pd-catalyzed anaerobic oxidation of secondary alcohols and domino oxidation−arylation reactions

Landers, Brant, Berini, Christophe, Wang, Chao and Navarro Fernandez, Oscar (2011) (N-heterocyclic carbene)-Pd-catalyzed anaerobic oxidation of secondary alcohols and domino oxidation−arylation reactions. Journal of Organic Chemistry, 76 (5). pp. 1390-1397. ISSN 0022-3263

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Abstract

The use of commercially available (SIPr)Pd(cinnamyl)Cl (SIPr = 1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene) as a precatalyst for the anaerobic oxidation of secondary alcohols is described. The use of this complex allows for a drastic reduction in the reaction times and catalyst loading when compared to the unsaturated counterpart. This catalytic system is compatible with the use of microwave dielectric heating, decreasing even further catalyst loading and reaction times. Domino Pd-catalyzed oxidation−arylation reactions of secondary alcohols are also presented.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science
Depositing User: Deeptima Massey
Date Deposited: 20 May 2013 06:28
Last Modified: 20 May 2013 06:28
URI: http://srodev.sussex.ac.uk/id/eprint/44745
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