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Bis(pentalene)di-titanium: a bent double-sandwich complex with a very short Ti–Ti bond

journal contribution
posted on 2023-06-08, 15:54 authored by Alexander F R Kilpatrick, Jennifer C Green, Geoff Cloke, Nikolaos Tsoureas
The novel bimetallic bis(pentalene) complex Ti2(µ:?5,?5-Pn†)2 (Pn† = C8H4{SiiPr3-1,4}2) has been synthesised and structurally characterised. Structural data show a Ti–Ti distance of 2.399(2) Å, consistent with a strong metal–metal interaction, which DFT calculations best describe as a double bond with s and p components

History

Publication status

  • Published

Journal

Chemical Communications

ISSN

1359-7345

Publisher

Royal Society of Chemistry

Volume

49

Page range

9434-9436

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2013-09-27

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