Bis(pentalene)di-titanium: a bent double-sandwich complex with a very short Ti–Ti bond

Kilpatrick, Alexander F R, Green, Jennifer C, Cloke, F Geoffrey N and Tsoureas, Nikolaos (2013) Bis(pentalene)di-titanium: a bent double-sandwich complex with a very short Ti–Ti bond. Chemical Communications, 49. pp. 9434-9436. ISSN 1359-7345

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Abstract

The novel bimetallic bis(pentalene) complex Ti2(μ:η5,η5-Pn†)2 (Pn† = C8H4{SiiPr3-1,4}2) has been synthesised and structurally characterised. Structural data show a Ti–Ti distance of 2.399(2) Å, consistent with a strong metal–metal interaction, which DFT calculations best describe as a double bond with σ and π components

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science
Depositing User: Deeptima Massey
Date Deposited: 27 Sep 2013 13:01
Last Modified: 27 Sep 2013 13:01
URI: http://srodev.sussex.ac.uk/id/eprint/46462
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