Tools
Hitchcock, Peter B, Lappert, Michael F, Maren, Laurent and Protchenko, Andrey V (2008) Lanthanum does form stable molecular compounds in the +2 oxidation state. Angewandte Chemie International Edition, 47 (8). pp. 1488-1491. ISSN 1433-7851
Full text not available from this repository.
Official URL: http://dx.doi.org/10.1002/anie.200704887
Abstract
Getting down to business: Reduction of the LaIII tricyclopentadienide complex [LaCp′′3] (Cp′′=η5-1,3-(SiMe3)2C5H3) by K and [18]crown-6 or [2,2,2]cryptand produced thermally stable mononuclear crystalline lanthanate(II) salts. The La +2 oxidation state in these complexes was confirmed both in solution (EPR) and the solid state (EPR, SQUID, X-ray diffraction) and was supported by a computational study.
Item Type: | Article |
---|---|
Schools and Departments: | School of Life Sciences > Chemistry |
Subjects: | Q Science |
Depositing User: | Deeptima Massey |
Date Deposited: | 11 Oct 2013 07:14 |
Last Modified: | 11 Oct 2013 07:14 |
URI: | http://srodev.sussex.ac.uk/id/eprint/46631 |