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Syntheses, structural studies, photoelectron spectra and density functional theory calculations of the “pseudo” tetraphospha-metallocenes [M(?-P2C3But3)2], (M = Ni, Pd, Pt)

journal contribution
posted on 2023-06-08, 16:02 authored by Geoff Cloke, Jennifer C Green, Peter B Hitchcock, John F Nixon, James L Suter, D James Wilson
Syntheses and structural characterization of the complexes [M(?-P2C3But3)2], (M = Ni, Pd, Pt) are described. The nickel compound has an 18-electron [Ni(?5-P2C3But3)(?3-P2C3But3)] structure, whereas the palladium and platinum compounds both have a 16-electron [M(?3-P2C3But3)2] structure (M = Pd, Pt).The electronic structure is examined and discussed using both photoelectron spectroscopy and DFT calculations.

History

Publication status

  • Published

Journal

Dalton Transactions

ISSN

1477-9226

Page range

1164-1171

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2013-10-11

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