Syntheses, structural studies, photoelectron spectra and density functional theory calculations of the “pseudo” tetraphospha-metallocenes [M(η-P2C3But3)2], (M = Ni, Pd, Pt)

Cloke, F Geoffrey N, Green, Jennifer C, Hitchcock, Peter B, Nixon, John F, Suter, James L and Wilson, D James (2009) Syntheses, structural studies, photoelectron spectra and density functional theory calculations of the “pseudo” tetraphospha-metallocenes [M(η-P2C3But3)2], (M = Ni, Pd, Pt). Dalton Transactions. pp. 1164-1171. ISSN 1477-9226

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Abstract

Syntheses and structural characterization of the complexes [M(η-P2C3But3)2], (M = Ni, Pd, Pt) are described. The nickel compound has an 18-electron [Ni(η5-P2C3But3)(η3-P2C3But3)] structure, whereas the palladium and platinum compounds both have a 16-electron [M(η3-P2C3But3)2] structure (M = Pd, Pt).The electronic structure is examined and discussed using both photoelectron spectroscopy and DFT calculations.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science
Depositing User: Deeptima Massey
Date Deposited: 11 Oct 2013 05:25
Last Modified: 11 Oct 2013 05:25
URI: http://srodev.sussex.ac.uk/id/eprint/46635
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