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Brown, W A, Gardner, P, Perez Jigato, M and King, D A (1995) Characterization and orientation of adsorbed NO dimers on Ag{111} at low temperatures. Journal of Chemical Physics, 102 (18). 7277 - 7280. ISSN 0021-9606
Full text not available from this repository.Abstract
Reflection‐absorption infrared spectroscopy (RAIRS) and near‐edge x‐ray absorption fine structure(NEXAFS) have been used, with isotopic 14NO/15NO mixtures, to determine the structure and orientation of the monolayer species formed by NO adsorption on Ag{111} at 40 to 60 K. The adlayer is composed of NO dimers bonded with the N–N axis in the surface plane and with the molecular plane tilted away from the surface normal by about 30°. This structure provides a simple basis for understanding the facile reaction to adsorbed N2O and O which occurs on heating to 70 to 90 K.
| Item Type: | Article |
|---|---|
| Schools and Departments: | School of Life Sciences > Chemistry |
| Subjects: | Q Science |
| Depositing User: | Deeptima Massey |
| Date Deposited: | 22 Jul 2014 09:36 |
| Last Modified: | 22 Jul 2014 09:36 |
| URI: | http://srodev.sussex.ac.uk/id/eprint/48655 |