Braunschweig, Holger, Ye, Qing, Vargas, Alfredo, Dewhurst, Rian D and Hupp, Florian (2014) Complete and partial 1,2-additions across transition metal-boron double bonds. Journal of the American Chemical Society. ISSN 1520-5126

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Abstract

The first 1,2-additions across a metal-boron double bond are reported, one a definitive chlorogallation of a Fe=B bond, the other a partial chlorogallation of a Mo=B bond that leads to a highly unusual, planar Mo-B-Ga-Cl rhombus. The two reactions occur with opposite regiochemistry, with the Ga atom bound to the Fe atom in the former and to both the Mo and B atoms in the latter. The bonding in the Mo adduct, as well as the reasons for the differing regiochemistry of the reaction, are explored computationally.

Item Type:	Article
Schools and Departments:	School of Life Sciences > Chemistry
Subjects:	Q Science > QD Chemistry
Depositing User:	Alfredo Vargas
Date Deposited:	25 Jun 2014 10:32
Last Modified:	25 Jun 2014 13:42
URI:	http://srodev.sussex.ac.uk/id/eprint/49063

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