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Olefin cross-metathesis/Suzuki–Miyaura reactions on vinylphenylboronic acid pinacol esters

journal contribution
posted on 2023-06-08, 18:33 authored by Christine B Baltus, Irina Chuckowree, Neil J Press, Iain Day, Simon J Coles, Graham J Tizzard, John SpencerJohn Spencer
A series of alkenyl phenylboronic acid pinacol esters has been synthesized via an olefin cross-metathesis reaction of vinylphenylboronic acid pinacol ester derivatives. After catalytic hydrogenation, the resulting boronates were coupled via a microwave-mediated Suzuki–Miyaura reaction to afford a library of biarylethyl aryl and biarylethyl cycloalkyl derivatives. A complementary reaction sequence involved an initial Suzuki–Miyaura coupling.

History

Publication status

  • Published

Journal

Tetrahedron Letters

ISSN

0040-4039

Publisher

Elsevier

Issue

10

Volume

54

Page range

1211-1217

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2014-09-30

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