ejic.201402649-accepted manuscript.pdf (614.17 kB)
Synthesis, structures and coordination chemistry of singly bridged phosphane-boranes with coordinately unsaturated platinum group metals
journal contribution
posted on 2023-06-08, 18:40 authored by Victoria Greenacre, Melvyn Ansell, Mark Roe, Ian CrossleyIan CrossleyA range of singly bridged phosphane-boranes (PBs) have been investigated as potential ligands for basic transition metals. The PBs Ph2PC(Ph)=C(R)BR2 (R = Bu 1, Ph 2, Et 3), based on a rigid cis-ethylene bridges, have been prepared, improving upon limited literature precedent. All three compounds have been comprehensively characterised for the first time, including by X-ray diffraction studies. Significant intramolecular P?B association is apparent in each case, which serves to preclude their engagement as ligands. In contrast, the more flexible PBs R2P(CH2)2BBN (R = Fu 5, Ph 6) readily coordinate to the platinum group metals Pt, Pd and Rh. These complexes have been fully characterised, including an X-ray diffraction study of [Rh(CO){Fu2P(CH2)2-BBN}2Cl] (13).
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Publication status
- Published
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- Accepted version
Journal
European Journal of Inorganic ChemistryISSN
1434-1948Publisher
John Wiley & SonsExternal DOI
Issue
29Volume
2014Page range
5053-5062Department affiliated with
- Chemistry Publications
Full text available
- Yes
Peer reviewed?
- Yes
Legacy Posted Date
2014-10-13First Open Access (FOA) Date
2018-08-15First Compliant Deposit (FCD) Date
2019-07-02Usage metrics
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