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Ritter type reactions of N-Chlorosaccharin: a method for the electrophilic diamination of alkenes
journal contribution
posted on 2023-06-08, 19:30 authored by Kevin I Booker-Milburn, Dominic J Guly, Brian Cox, Panayiotis A ProcopiouN-Chlorosaccharin has been shown to undergo electrophilic Ritter-type reactions with alkenes in acetonitrile. The resulting labile ß-chloro sulfonylamidines can be ring-opened and cyclized to imidazolines. Overall this provides a one pot method for the electrophilic diamination of alkenes. Competing aziridine formation as well as allylic chlorination are also observed depending on the nature of the alkene used.
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Publication status
- Published
Journal
Organic LettersISSN
1523-7060Publisher
American Chemical SocietyExternal DOI
Issue
18Volume
5Page range
3313-3315Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2015-01-13Usage metrics
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