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Reductive deoxygenation of CO2 by a bimetallic titanium bis(pentalene) complex
journal contribution
posted on 2023-06-08, 20:14 authored by Alexander F R Kilpatrick, Geoff ClokeThe bimetallic bis(pentalene) complex (µ:?5,?5-Pn†)2Ti2 reductively splits CO2 to form a bis(oxo) bridged dimer [(?8-Pn†)Ti(µ-O)]2, in which the Ti–Ti bond has been cleaved, and the dicarbonyl complex (µ:?5,?5-Pn†)2[Ti(CO)]2.
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Publication status
- Published
Journal
Chemical CommunicationsISSN
1359-7345Publisher
Royal Society of ChemistryExternal DOI
Volume
50Page range
2769-2771Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2015-03-09Usage metrics
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