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Influence of the metal salt on the self-assembly of isophthaloylbis-ß-alanine and Cu(II) ion

journal contribution
posted on 2023-06-08, 20:16 authored by Smaragda Lymperopoulou, Vassiliki N Dokorou, Athanassios C Tsipis, Peter G Weidler, John C Plakatouras, Annie K Powell, George KostakisGeorge Kostakis
The initial employment of the new pseudopeptidic ligand isophthaloylbis-ß-alanine (H2IBbA, H2L) with CuII ion affords a one dimensional (1D) [Cu2L2(H2O)(CH3OH)]·2H2O·CH3OH (1) and a two dimensional (2D) [Cu2L2(H2O)4]·6H2O (2) compound, respectively, illustrating the important influence of the metal salt and the solvent system used in determining the motif of the final product. Infrared spectroscopy, thermal, adsorption and theoretical studies of these compounds are also discussed.

History

Publication status

  • Published

Journal

Polyhedron

ISSN

0277-5387

Publisher

Elsevier

Volume

89

Page range

313-321

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2015-03-10

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    University of Sussex (Publications)

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