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ß-diketiminato organolead complexes: structures,207Pb NMR, and Hammett correlations
journal contribution
posted on 2023-06-08, 20:42 authored by Morgan J Taylor, Emma J Coakley, Martyn P Coles, Hazel CoxHazel Cox, J Robin FultonThe synthesis, structure, and spectroscopic details of a series of ß-diketiminato lead(II) alkyl complexes are described. The Hammett correlation between the 207Pb NMR chemical shifts and spara Hammett constant was examined computationally and found to be due to the paramagnetic shielding contribution, whereas the diamagnetic and spin–orbit coupling contributions remained fairly constant across this series of compounds.
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Publication status
- Published
Journal
OrganometallicsISSN
0276-7333Publisher
American Chemical SocietyExternal DOI
Issue
11Volume
34Page range
2515-2521Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2015-05-07Usage metrics
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