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Dative bonding between group 13 elements using a boron-centered Lewis base
journal contribution
posted on 2023-06-08, 22:45 authored by Holger Braunschweig, Rian D Dewhurst, Leanne Pentecost, Krzysztof Radacki, Alfredo VargasAlfredo Vargas, Qing YeAn electron-rich monovalent boron compound is used as a Lewis base to prepare adducts with group 13 Lewis acids using both its boron and nitrogen sites. The hard Lewis acid AlCl3 binds through a nitrogen atom of the Lewis base, while softer Lewis acids GaX3 (Cl, Br, I) bind at the boron atom. The latter are the first noncluster Lewis adducts between a boron-centered Lewis base and a main-group Lewis acid.
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Publication status
- Published
Journal
Angewandte Chemie International EditionISSN
1433-7851Publisher
Wiley-VCH Verlag GmbH & Co. KGaA, WeinheimExternal DOI
Issue
1Volume
55Page range
436-440Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2015-11-25Usage metrics
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