Chen, Long, Willcock, Helen, Wedge, Christopher J, Hartl, František, Colquhoun, Howard M and Greenland, Barnaby (2015) Efficient access to conjugated 4,4′-bipyridinium oligomers using the Zincke reaction: synthesis, spectroscopic and electrochemical properties. Organic and Biomolecular Chemistry (14). pp. 980-988. ISSN 1477-0520
![]() |
PDF
- Published Version
Available under License Creative Commons Attribution. Download (2MB) |
Abstract
The cyclocondensation reaction between rigid, electron-rich aromatic diamines and 1,1′-bis(2,4-dinitrophenyl)-4,4′-bipyridinium (Zincke) salts has been harnessed to produce a series of conjugated oligomers containing up to twelve aromatic/heterocyclic residues. These oligomers exhibit discrete, multiple redox processes accompanied by dramatic changes in electronic absorption spectra.
Item Type: | Article |
---|---|
Schools and Departments: | School of Life Sciences > Chemistry |
Subjects: | Q Science > QD Chemistry > QD0241 Organic chemistry |
Depositing User: | Barnaby Greenland |
Date Deposited: | 09 Feb 2018 16:12 |
Last Modified: | 09 Feb 2018 16:45 |
URI: | http://srodev.sussex.ac.uk/id/eprint/73454 |
View download statistics for this item
📧 Request an update