Tools
Arrowsmith, Merle, Mattock, James D, Hagspiel, Stephan, Krummenacher, Ivo, Vargas, Alfredo and Braunschweig, Holger (2018) Facile synthesis of a stable dihydroboryl {BH2}– anion. Angewandte Chemie International Edition, 57 (46). pp. 15272-15275. ISSN 1433-7851
![]() |
PDF
- Accepted Version
Restricted to SRO admin only until 20 September 2019. Download (1MB) |
Official URL: http://dx.doi.org/10.1002/anie.201809983
Abstract
While the one-electron reduction of (CAACMe)BH2Br (CAACMe = 1-(2,6-diisopropylphenyl)-3,3,5,5-tetramethylpyrrolidin-2-ylidene) yields a hydride-shift isomer of the corresponding tetrahydrodiborane, a further reversible reduction leads to the first stable parent boryl anion, [(CAACMe)BH2]–, which acts as a powerful boron nucleophile.
Item Type: | Article |
---|---|
Schools and Departments: | School of Life Sciences > Chemistry |
Subjects: | Q Science > QD Chemistry |
Depositing User: | Alfredo Vargas |
Date Deposited: | 25 Sep 2018 13:49 |
Last Modified: | 06 Dec 2018 14:25 |
URI: | http://srodev.sussex.ac.uk/id/eprint/78988 |
View download statistics for this item
📧 Request an update