Manuscript Diiododiborenes_final.pdf (773.27 kB)
Phosphine stabilized diiododiborenes: isolable diborenes with six labile bonds
journal contribution
posted on 2023-06-09, 16:55 authored by Jonas H Muessig, Melanie Thaler, Rian D Dewhurst, Valerie Paprocki, Jens Seufert, James D Mattock, Alfredo VargasAlfredo Vargas, Holger BraunschweigThe lability of B=B, B-P and B-halide bonds is combined in the syntheses of the first diiododiborenes. In a series of reactivity tests, these diiododiborenes demonstrate cleavage of all six of their central bonds in different ways, leading to products of B=B hydrogenation and dihalogenation as well as halide exchange.
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Publication status
- Published
File Version
- Accepted version
Journal
Angewandte Chemie International EditionISSN
1433-7851Publisher
WileyExternal DOI
Issue
13Volume
131Page range
4451-4456Department affiliated with
- Chemistry Publications
Full text available
- Yes
Peer reviewed?
- Yes
Legacy Posted Date
2019-02-25First Open Access (FOA) Date
2020-02-04First Compliant Deposit (FCD) Date
2019-02-25Usage metrics
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